Welcome to the GLA forum Tara. Sorry to hear your mileage experience, would seem like you should have better performance. I see from your photos that you're driving in the Economy mode as you mentioned, but you didn't say if you are using the minimum octane fuel requirement, 91 or 92. How is your ECO start/stop system working? That can gain a mile or two per gallon depending on varying circumstances.
Also, in your 114 mile drive, do you have a lot of traffic or stoplights? Do you do other short distance travel besides the 114 mile trip? One of the console screens monitors your realtime mileage performance, up and down as you drive, as opposed to the average mileage screens you showed. That could give you valuable insight to what's sucking down fuel. I am averaging about 26 MPG in short distance island driving in the Comfort mode, so your experience might not be too far off expectations. I've only gotten over 30 MPG once when I drove one of our three freeways that goes 20 miles or so. Would love to see how I'd do on a US mainland long distance trip.
Most of all, are you doing full fill-ups to the same point (usually the first nozzle click) and resetting all your screens to the default settings, as well as doing manual math of trip odometer miles divided by gallons of fuel to compare numbers? It might be your computer readout is skewed by not getting reset upon fill up. I find the two rarely agree for me, with no real correlation either way.
BTW, if 82 MPH is your standard speed, that might be a clue as well.